Glacial acetic acid, also known as acetic acid anhydrous or ethanoic acid, is a cornerstone substance in both industrial and laboratory settings. Its purity and concentrated form make it indispensable across various sectors. Understanding its physical properties enhances both safety and efficiency in its use, and is crucial for experts dealing with chemical products.

Boiling Point and Melting Point Glacial acetic acid has a boiling point of approximately 118.1°C (244.5°F) and a melting point of 16.6°C (61.9°F). These properties are significant for industrial applications where phase transition knowledge is essential for process optimization. For instance, in pharmaceuticals, precise temperature control is necessary to maintain stability during synthesis and formulation stages.
Density and Viscosity With a density of 1.05 g/cm³ at 25°C, glacial acetic acid is denser than water. This high density implies that it can be easily separated from non-polar solvents in purification processes. Its viscosity is around 1.22 mPa·s at 25°C, a critical factor when considering its use as a solvent or acidulant in various chemical reactions and formulations.

Solubility Glacial acetic acid is highly soluble in water, alcohol, and ether, which indicates its versatility in countless applications ranging from food additives to chemical manufacturing. The complete miscibility with water allows it to adjust the pH levels in solutions efficiently, facilitating its function as a reliable acidifying agent.
Acidity Displaying a pKa value of around 4.76,
glacial acetic acid is a weak acid. However, its anhydrous nature means that in its concentrated form, it can exhibit much stronger acidic behavior compared to its diluted solutions. This property is particularly valuable in organic synthesis where controlled acidic conditions are prerequisite to drive certain chemical transformations.
glacial acetic acid physical properties
Hygroscopic Nature Glacial acetic acid is hygroscopic, which means it has the ability to absorb moisture from the environment. This characteristic requires adequate storage solutions to prevent its dilution and maintain its efficacy. The hygroscopic nature is beneficial where water-sensitive reactions are carried out, offering control over moisture levels without additional dehydration steps.
Corrosiveness An authoritative aspect of working with glacial acetic acid is recognizing its corrosive nature, especially toward metals and organic materials. As such, understanding the materials compatibility is crucial when designing storage or transport containers. Safety measures in industrial plants ensure that exposure risks are minimized, safeguarding both personnel and equipment.
Appearance and Odor This acid appears as a clear, colorless liquid, often described as having a distinctly pungent vinegar-like odor, a characteristic indicating its purity and presence. The perceivable odor serves as an immediate identifier in quality control processes, allowing for quick detection of any impurities or contaminations.
In the realm of product manufacturing, these distinctive physical properties of glacial acetic acid are invaluable for optimizing production strategies and ensuring product quality. Its role extends from being a critical solvent, reactant, or reagent to an essential acidulant, emphasizing its multifaceted application across industries. By leveraging its properties strategically, industries can achieve heightened efficiency and innovation, driving advancements that are both economically and technically beneficial.