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While glacial acetic acid is an essential chemical in many fields, its toxicity cannot be overlooked. Understanding the risks associated with its use and implementing appropriate safety measures are crucial for safeguarding health and the environment. Proper training, stringent safety protocols, and awareness of emergency procedures can help prevent accidents and limit exposure, ensuring that the benefits of glacial acetic acid can be harnessed without compromising safety.

The physical properties of these two forms also highlight their differences. Anhydrous acetic acid is a liquid that has a strong, pungent smell and is highly volatile, which can pose safety risks if not handled correctly. It is also corrosive and can cause severe burns upon contact with skin. Conversely, glacial acetic acid, while also hazardous, is often less volatile than its anhydrous counterpart and can form solid crystals when cooled. Both forms are flammable and should be handled with caution in well-ventilated areas, and personal protective equipment (such as gloves and goggles) is recommended.